Issue 12, 2004
From the journal:

Dalton Transactions

Gold–thallium supramolecular arrays with 4,4′-bipyridine. Solvent induction of luminescent networks

Eduardo J. Fernández,*a   Antonio Laguna,*b   José María López-de-Luzuriaga,b   M. Elena Olmosb  and  Javier Pérezb  

* Corresponding authors

a Departamento de Química, Universidad de la Rioja, Grupo de Síntesis Química de La Rioja, UA-CSIC, Complejo Científico Tecnológico, Logroño, Spain
E-mail: eduardo.fernandez@dq.unirioja.es

b Departamento de Química Inorgánica, Instituto de Ciencia de Materiales de Aragón, Universidad de Zaragoza-CSIC, Zaragoza, Spain
E-mail: alaguna@posta.unizar.es

Abstract

The reaction of [AuTl(C6Cl5)2]n with bipy at different molar ratios, solvents or crystallisation conditions affords a series of two- and three-dimensional luminescent complexes, [AuTl(C6Cl5)2(bipy)0.5]n, [AuTl(C6Cl5)2(bipy)]n, {[Tl(bipy)] [Tl(bipy)0.5(THF)][Au(C6Cl5)2]2}n, {[Tl(bipy)][Tl(bipy)0.5(THF)][Au(C6Cl5)2]2·THF}n and {[AuTl(C6Cl5)2(bipy)]·0.5toluene}n (bipy = 4,4′-bipyridine; THF = tetrahydrofuran) all of them containing polymeric chains formed via unsupported Au⋯Tl interactions and bridging bipyridine ligands.

Graphical abstract: Gold–thallium supramolecular arrays with 4,4′-bipyridine. Solvent induction of luminescent networks

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Article information

DOI
https://doi.org/10.1039/B404703F
Article type
Paper
Submitted
30 Mar 2004
Accepted
04 May 2004
First published
19 May 2004

Dalton Trans., 2004, 1801-1806

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Gold–thallium supramolecular arrays with 4,4′-bipyridine. Solvent induction of luminescent networks

E. J. Fernández, A. Laguna, J. M. López-de-Luzuriaga, M. E. Olmos and J. Pérez, Dalton Trans., 2004, 1801 DOI: 10.1039/B404703F

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