Issue 9, 2004

Evidence for C60 dimerisation in the fulleride [Cr(C9H12)2]+C60

Abstract

We report a detailed study of the structure, dynamics and electronic structure of the new fulleride [Cr(C9H12)2]+C60. Using a variety of characterization tools including EPR, NMR, SQUID magnetic measurements and high resolution X-ray powder diffraction a spin pairing of the C60 spins with decreasing temperatures could be observed. Contrary to the observed phase transition of first order in the related compound [Cr(C6H9)2]+C60 the phase transition observed in the title compound is of higher order.

Article information

Article type
Paper
Submitted
05 Jan 2004
Accepted
16 Feb 2004
First published
18 Mar 2004

Phys. Chem. Chem. Phys., 2004,6, 2454-2460

Evidence for C60 dimerisation in the fulleride [Cr(C9H12)2]+C60

A. Hönnerscheid, L. van Wüllen, R. Dinnebier, M. Jansen, J. Rahmer and M. Mehring, Phys. Chem. Chem. Phys., 2004, 6, 2454 DOI: 10.1039/B317060H

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