Issue 87, 2004
From the journal:

CrystEngComm

Square-pyramidal bonding of I2 molecules at the I− nodes of a polyiodide infinite pseudo-cubic 3D-network

M. Carla Aragoni,a   Massimiliano Arca,*a   Francesco A. Devillanova,a   Michael B. Hursthouse,b   Susanne L. Huth,b   Francesco Isaia,a   Vito Lippolisa  and  Annalisa Mancinia  

* Corresponding authors

a Dipartimento di Chimica Inorganica ed Analitica, Università degli Studi di Cagliari, S.S. 554 bivio per Sestu, 09042 Monserrato, Cagliari, Italy
E-mail: marca@unica.it

b Department of Chemistry, University of Southampton, Highfield, Southampton, UK

Abstract

The reaction of di-[2]-pyridyl-disulfide (L) with diiodine in molar ratios ranging between 1 : 0.5 and 1 : 5 afforded [(HL+)(I−)·5/2I2] as the only product, containing the first example of a self-assembled infinite polyiodide pseudo-cubic 3D-network featuring distorted square pyramidal I−·5I2 moieties at the nodes.

Graphical abstract: Square-pyramidal bonding of I2 molecules at the I− nodes of a polyiodide infinite pseudo-cubic 3D-network

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Article information

DOI
https://doi.org/10.1039/B415415K
Article type
Communication
Submitted
05 Oct 2004
Accepted
07 Oct 2004
First published
18 Oct 2004

CrystEngComm, 2004,6, 540-542

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Square-pyramidal bonding of I2 molecules at the I− nodes of a polyiodide infinite pseudo-cubic 3D-network

M. Carla Aragoni, M. Arca, F. A. Devillanova, M. B. Hursthouse, S. L. Huth, F. Isaia, V. Lippolis and A. Mancini, CrystEngComm, 2004, 6, 540 DOI: 10.1039/B415415K

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