Issue 23, 2004
From the journal:

CrystEngComm

Novel dienone-based ligands for the synthesis of coordination polymers

Sergey Z. Vatsadze,*a   Marina A. Kovalkina,a   Natal'ya V. Sviridenkova,a   Nikolai V. Zyk,a   Andrei V. Churakov,b   Lyudmila G. Kuz'minab  and  Judith A. K. Howardc  

* Corresponding authors

a Department of Chemistry, Moscow State University, Leninskie Gory, Moscow, Russia
E-mail: szv@org.chem.msu.ru
Fax: (095) 939 0290

b Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninskii pr. 31, Moscow, Russia
E-mail: churakov@igic.ras.ru
Fax: (095) 954 1279

c Department of Chemistry, University of Durham, South Road, Durham, UK
E-mail: j.a.k.howard@durham.ac.uk
Fax: (191) 374 3745

Abstract

New angular exo-dentate 3,3′-bipyridyl-type ligand [L = 2,6-di(3-pyridylmethylidene)cyclohexanone, 1] with conjugated dienone system was used for the synthesis of {[AgL]NO3}n, 2. An X-ray structural determination showed that 2 is composed of polymeric chains (–Ag–L–)n, twinned via metallophilic and stacking interaction.

Graphical abstract: Novel dienone-based ligands for the synthesis of coordination polymers

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Article information

DOI
https://doi.org/10.1039/B402418D
Article type
Paper
Submitted
17 Feb 2004
Accepted
05 Apr 2004
First published
13 Apr 2004

CrystEngComm, 2004,6, 112-115

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Novel dienone-based ligands for the synthesis of coordination polymers

S. Z. Vatsadze, M. A. Kovalkina, N. V. Sviridenkova, N. V. Zyk, A. V. Churakov, L. G. Kuz'mina and J. A. K. Howard, CrystEngComm, 2004, 6, 112 DOI: 10.1039/B402418D

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