Issue 23, 2004
From the journal:

Chemical Communications

Donor-rich and acceptor-rich pyridine-phosphadiazonium adducts: Diversifying the Lewis acceptor chemistry of phosphorus(iii)†

Neil Burford,*a   Heather A. Spinney,a   Michael J. Fergusonb  and  Robert McDonaldb  

* Corresponding authors

a Department of Chemistry, Dalhousie University, Halifax, Nova Scotia, Canada
E-mail: Neil.Burford@dal.ca
Fax: (1)902-494-1310
Tel: (1)902-494-3190

b X-Ray Crystallography Laboratory, Department of Chemistry, University of Alberta, Edmonton, Alberta, Canada
E-mail: Bob.McDonald@ualberta.ca
Fax: (1)780-492-8231
Tel: (1)780-492-2485

Abstract

[Mes*NP(DMAP)2][OTf] represents the first ligand-rich coordination complex of a phosphorus(III) Lewis acceptor, and a three coordinate hypervalent electron-rich (lone pair bearing) center; further diversification is demonstrated by, [(Mes*NP)2(4,4′-BIPY)][OTf]2, representing an acceptor-rich dication.

Graphical abstract: Donor-rich and acceptor-rich pyridine-phosphadiazonium adducts: Diversifying the Lewis acceptor chemistry of phosphorus(iii)

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Article information

DOI
https://doi.org/10.1039/B412267D
Article type
Communication
Submitted
09 Aug 2004
Accepted
27 Aug 2004
First published
11 Oct 2004

Chem. Commun., 2004, 2696-2697

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Donor-rich and acceptor-rich pyridine-phosphadiazonium adducts: Diversifying the Lewis acceptor chemistry of phosphorus(III)

N. Burford, H. A. Spinney, M. J. Ferguson and R. McDonald, Chem. Commun., 2004, 2696 DOI: 10.1039/B412267D

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