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Issue 22, 2004
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Enhanced selectivity in non-heme iron catalysed oxidation of alkanes with peracids: evidence for involvement of Fe(IV)[double bond, length as m-dash]O species

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Abstract

Catalytic alkane oxidation with high selectivity using peracids and an (N4Py)Fe complex is presented and the role of [(N4Py)Fe(IV)[double bond, length as m-dash]O]2+ species, molecular oxygen and hydroxyl radicals in the catalysis is discussed.

Graphical abstract: Enhanced selectivity in non-heme iron catalysed oxidation of alkanes with peracids: evidence for involvement of Fe(iv) [[double bond, length as m-dash]] O species

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Publication details

The article was received on 05 Aug 2004, accepted on 14 Sep 2004 and first published on 14 Oct 2004


Article type: Communication
DOI: 10.1039/B412016G
Chem. Commun., 2004, 2550-2551

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    Enhanced selectivity in non-heme iron catalysed oxidation of alkanes with peracids: evidence for involvement of Fe(IV)[double bond, length as m-dash]O species

    T. A. van den Berg, J. W. de Boer, W. R. Browne, G. Roelfes and B. L. Feringa, Chem. Commun., 2004, 2550
    DOI: 10.1039/B412016G

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