Issue 24, 2004
From the journal:

Chemical Communications

Reactivity of a N-heterocyclic carbene, 1,3-di-(1-adamantyl) imidazol-2-ylidene, with a pseudo-acid: structural characterization of Claisen condensation adduct†

Gabriela A. Grasa,‡a   Rohit Singh,a   Natalie M. Scott,a   Edwin D. Stevensa  and  Steven P. Nolan*a  

* Corresponding authors

a Department of Chemistry, University of New Orleans, New Orleans, USA
E-mail: snolan@uno.edu
Fax: +1 504 280 6860
Tel: +1 504 280 6445

Abstract

The reactivity of a N-heterocyclic carbene (NHC) with a pseudo-acid (ester in this case) is described. The product results from an unusual C–H bond activation. The structure of the product has been established by a single crystal diffraction study.

Graphical abstract: Reactivity of a N-heterocyclic carbene, 1,3-di-(1-adamantyl) imidazol-2-ylidene, with a pseudo-acid: structural characterization of Claisen condensation adduct

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Article information

DOI
https://doi.org/10.1039/B410986D
Article type
Communication
Submitted
19 Jul 2004
Accepted
16 Sep 2004
First published
04 Nov 2004

Chem. Commun., 2004, 2890-2891

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Reactivity of a N-heterocyclic carbene, 1,3-di-(1-adamantyl) imidazol-2-ylidene, with a pseudo-acid: structural characterization of Claisen condensation adduct

G. A. Grasa, R. Singh, N. M. Scott, E. D. Stevens and S. P. Nolan, Chem. Commun., 2004, 2890 DOI: 10.1039/B410986D

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