Issue 22, 2004
From the journal:

Chemical Communications

The substituent-dependent base-treatment chemistry of (η5-C5H5)Fe(CO)2SiR2SiR2Cl: formation of 1,2-disila-3-metallacyclobutanes, their ring-opened polymers, migrations and substitutions†

Hemant K. Sharmaa  and  Keith H. Pannell*a  

* Corresponding authors

a Department of Chemistry, University of Texas at El Paso, El Paso, TX, USA
E-mail: kpannell@utep.edu

Abstract

We report the formation of disilametallacycles, high molecular weight polymers or simple substitution products from the reactions of 1-(cyclopentadienyliron dicarbonyl)-2-chlorodisilanes with bases, LDA or n-BuLi.

Graphical abstract: The substituent-dependent base-treatment chemistry of (η5-C5H5)Fe(CO)2SiR2SiR2Cl: formation of 1,2-disila-3-metallacyclobutanes, their ring-opened polymers, migrations and substitutions

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/B410822A
Article type
Communication
Submitted
15 Jul 2004
Accepted
02 Sep 2004
First published
06 Oct 2004

Chem. Commun., 2004, 2556-2557

Permissions

Request permissions

The substituent-dependent base-treatment chemistry of (η5-C5H5)Fe(CO)2SiR2SiR2Cl: formation of 1,2-disila-3-metallacyclobutanes, their ring-opened polymers, migrations and substitutions

H. K. Sharma and K. H. Pannell, Chem. Commun., 2004, 2556 DOI: 10.1039/B410822A

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements