Issue 21, 2004

The first tandem double palladium-catalyzed aminations: synthesis of dipyrido[1,2-a∶3′,2′-d]imidazole and its benzo- and aza-analogues

Abstract

A new strategy for the synthesis of the title compounds via a regio- and chemoselective one-pot inter- and intramolecular Buchwald–Hartwig amination of 2-chloro-3-iodopyridine with aminoazines and -diazines is reported.

Graphical abstract: The first tandem double palladium-catalyzed aminations: synthesis of dipyrido[1,2-a∶3′,2′-d]imidazole and its benzo- and aza-analogues

Article information

Article type
Communication
Submitted
17 Jun 2004
Accepted
06 Aug 2004
First published
20 Sep 2004

Chem. Commun., 2004, 2466-2467

The first tandem double palladium-catalyzed aminations: synthesis of dipyrido[1,2-a∶3′,2′-d]imidazole and its benzo- and aza-analogues

K. T. J. Loones, B. U. W. Maes, R. A. Dommisse and G. L. F. Lemière, Chem. Commun., 2004, 2466 DOI: 10.1039/B409161B

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