Issue 22, 2004
From the journal:

Chemical Communications

Highly efficient epoxidation method of olefins with hydrogen peroxide as terminal oxidant, bicarbonate as a co-catalyst and oxodiperoxo molybdenum(vi) complex as catalyst†

Narottam Gharah,a   Santu Chakraborty,b   Alok K. Mukherjeeb  and  Ramgopal Bhattacharyya*a  

* Corresponding authors

a Department of Chemistry, Jadavpur University, Kolkata – 700 032, India
E-mail: argibhatta@yahoo.co.in
Fax: (+91)(+33) 2414-6584
Tel: (+91) (+33) 2414-6193

b Department of Physics, Jadavpur University, Kolkata – 700 032, India

Abstract

A combination of the newly synthesized and structurally characterized compound, [MoO(O2)2(saloxH)] (saloxH2 = salicylaldoxime) as catalyst, H2O2 as terminal oxidant and NaHCO3 as co-catalyst when stirred in CH3CN (10 cm3) at room temperature (rt) shows a very pronounced efficiency epoxidation of olefinic compounds, the method being green and economical.

Graphical abstract: Highly efficient epoxidation method of olefins with hydrogen peroxide as terminal oxidant, bicarbonate as a co-catalyst and oxodiperoxo molybdenum(vi) complex as catalyst

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Article information

DOI
https://doi.org/10.1039/B408946D
Article type
Communication
Submitted
11 Jun 2004
Accepted
06 Aug 2004
First published
28 Sep 2004

Chem. Commun., 2004, 2630-2632

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Highly efficient epoxidation method of olefins with hydrogen peroxide as terminal oxidant, bicarbonate as a co-catalyst and oxodiperoxo molybdenum(VI) complex as catalyst

N. Gharah, S. Chakraborty, A. K. Mukherjee and R. Bhattacharyya, Chem. Commun., 2004, 2630 DOI: 10.1039/B408946D

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