Issue 18, 2004
From the journal:

Chemical Communications

Asymmetric radical additions of trialkylboranes to 2H-azirine-3-carboxylates

Erik Risberg,a   Andreas Fischerb  and  Peter Somfai*a  

* Corresponding authors

a KTH Chemistry, Organic Chemistry, KTH, S-100 44 Stockholm, Sweden
E-mail: Somfai@kth.se
Fax: +46 8 791 2333
Tel: +46 8 790 6960

b KTH Chemistry, Inorganic Chemistry, KTH, S-100 44 Stockholm, Sweden

Abstract

Asymmetric additions of alkyl radicals, generated from R3B, to chiral 2H-azirine-3-carboxylates offer a new entry to enantio-enriched aziridines, and proceed with high diastereoselectivity when using 8-phenylmenthol as chiral auxiliary.

Graphical abstract: Asymmetric radical additions of trialkylboranes to 2H-azirine-3-carboxylates

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/B408532A
Article type
Communication
Submitted
07 Jun 2004
Accepted
13 Jul 2004
First published
20 Aug 2004

Chem. Commun., 2004, 2088-2089

Permissions

Request permissions

Asymmetric radical additions of trialkylboranes to 2H-azirine-3-carboxylates

E. Risberg, A. Fischer and P. Somfai, Chem. Commun., 2004, 2088 DOI: 10.1039/B408532A

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements