Issue 23, 2004
From the journal:

Chemical Communications

Synthesis and photocleavage of a new dimeric bis(o-nitrobenzyl) diether tether†

Nandita Madhavana  and  Mary S. Gin*a  

* Corresponding authors

a Department of Chemistry, University of Illinois at Urbana–Champaign, 600 S. Mathews Ave, Urbana, IL, 61801 USA
E-mail: mgin@scs.uiuc.edu
Fax: +1 (217) 244-8024
Tel: +1 (217) 244-2284

Abstract

A new photocleavable linker, 4,4′-bis(alkoxymethyl-3,3′-dinitro)biphenyl, is reported that undergoes photolysis at two positions to release two equivalents of primary, secondary, or benzylic alcohol in yields that are higher than those obtained from the analogous monomeric o-nitrobenzyl ethers.

Graphical abstract: Synthesis and photocleavage of a new dimeric bis(o-nitrobenzyl) diether tether

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Article information

DOI
https://doi.org/10.1039/B408482A
Article type
Communication
Submitted
03 Jun 2004
Accepted
08 Sep 2004
First published
14 Oct 2004

Chem. Commun., 2004, 2728-2729

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Synthesis and photocleavage of a new dimeric bis(o-nitrobenzyl) diether tether

N. Madhavan and M. S. Gin, Chem. Commun., 2004, 2728 DOI: 10.1039/B408482A

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