Issue 20, 2004
From the journal:

Chemical Communications

Spectrophotometric, EPR and kinetic characterisation of the >N–O• radical from 1-hydroxybenzotriazole, a key reactive species in mediated enzymatic oxidations

Carlo Galli,*a   Patrizia Gentili,a   Osvaldo Lanzalunga,a   Marco Lucarinib  and  Gian Franco Pedullib  

* Corresponding authors

a Dipartimento di Chimica, Università ‘La Sapienza’, P.le A. Moro 5, Roma, Italy
E-mail: carlo.galli@uniroma1.it
Fax: +39 06 490421

b Dipartimento di Chimica Organica ‘A. Mangini’, Bologna, Italy

Abstract

Characterisation of the aminoxyl (>N–O•) radical BTNO, generated from 1-hydroxybenzotriazole (HBT) by the one-electron oxidant CAN (a CeIV salt), confirms BTNO as the reactive intermediate in oxidations run with the laccase/HBT system.

Graphical abstract: Spectrophotometric, EPR and kinetic characterisation of the >N–O• radical from 1-hydroxybenzotriazole, a key reactive species in mediated enzymatic oxidations

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Article information

DOI
https://doi.org/10.1039/B407835G
Article type
Communication
Submitted
26 May 2004
Accepted
16 Jul 2004
First published
07 Sep 2004

Chem. Commun., 2004, 2356-2357

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Spectrophotometric, EPR and kinetic characterisation of the >N–O• radical from 1-hydroxybenzotriazole, a key reactive species in mediated enzymatic oxidations

C. Galli, P. Gentili, O. Lanzalunga, M. Lucarini and G. F. Pedulli, Chem. Commun., 2004, 2356 DOI: 10.1039/B407835G

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