Issue 17, 2004
From the journal:

Chemical Communications

Conversion of [Pt(SRf)2(PPh2 − n(C6F5)n + 1)2] ( n = 0 or 1, Rf[double bond, length as m-dash]C6HF4-4) through carbon–fluorine bond activation to [Pt(SRf)2(1,2-C6F4(SRf)-(PPh2))] and chiral [Pt(SRf)2(1,2-C6F4(SRf)(PPh(C6F5)))]†

Luis Villanueva,a   Maribel Arroyo,b   Sylvain Bernèsb  and  Hugo Torrens*a  

* Corresponding authors

a Facultad de Química, UNAM, Cd. Universitaria, 04510 México D.F., Mexico
E-mail: torrens@servidor.unam.mx

b Centro de Química, Instituto de Ciencias, Benemerita UniversidadAutonoma de Puebla, Blvd. 14 Sur 6303, San Manuel, 72570 Puebla, Puebla, Mexico

Abstract

Treatment of trans-[PtCl2(PPh2 − n(C6F5)n + 1)2] (n = 0 or 1) with Pb(SC6HF4-4)2 yields a mixture of monometallic cis/trans [Pt(SC6HF4-4)2(PPh2 − n(C6F5)n + 1)2], thiolate-bridged bimetallic cis/trans [Pt2(μ-SC6HF4-4)2(SC6HF4-4)2(PPh2 − n(C6F5)n + 1)2] and [Pt(SC6HF4-4)2(1,2-C6F4(SC6HF4-4)(PPh2 − n(C6F5)n)].

Graphical abstract: Conversion of [Pt(SRf)2(PPh2 − n(C6F5)n + 1)2] ( n = 0 or 1, Rf [[double bond, length as m-dash]] C6HF4-4) through carbon–fluorine bond activation to [Pt(SRf)2(1,2-C6F4(SRf)-(PPh2))] and chiral [Pt(SRf)2(1,2-C6F4(SRf)(PPh(C6F5)))]

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Article information

DOI
https://doi.org/10.1039/B407328B
Article type
Communication
Submitted
14 May 2004
Accepted
23 Jun 2004
First published
30 Jul 2004

Chem. Commun., 2004, 1942-1943

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Conversion of [Pt(SRf)2(PPh2 − n(C6F5)n + 1)2] ( n = 0 or 1, Rf[double bond, length as m-dash]C6HF4-4) through carbon–fluorine bond activation to [Pt(SRf)2(1,2-C6F4(SRf)-(PPh2))] and chiral [Pt(SRf)2(1,2-C6F4(SRf)(PPh(C6F5)))]

L. Villanueva, M. Arroyo, S. Bernès and H. Torrens, Chem. Commun., 2004, 1942 DOI: 10.1039/B407328B

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