Issue 19, 2004

Secondary coordination sphere controlled reversible geometry reorganisations in copper(ii) complexes

Abstract

Reversible geometry reorganisations are demonstrated by cis-3,5-diamino-trans-hydroxycyclohexane (cis,trans-DAHC) copper(II) fluoride complexes, with the concentration of water in the mother liquor controlling interconversion between blue crystals of 5-coordinate syn-[Cu(DAHC)2F](F)·2CH3OH·H2O and red crystals of 4-coordinate anti-[Cu(DAHC)2](F)2·2H2O.

Graphical abstract: Secondary coordination sphere controlled reversible geometry reorganisations in copper(ii) complexes

Supplementary files

Article information

Article type
Communication
Submitted
13 May 2004
Accepted
12 Jul 2004
First published
20 Aug 2004

Chem. Commun., 2004, 2156-2157

Secondary coordination sphere controlled reversible geometry reorganisations in copper(II) complexes

J. Fielden, D. Long and L. Cronin, Chem. Commun., 2004, 2156 DOI: 10.1039/B407229D

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