Platinum catalysed 3,4- and 1,4-diboration of α,β-unsaturated carbonyl compounds using bis-pinacolatodiboron

Nathan J. Bell; Andrew J. Cox; Neil R. Cameron; John S. O. Evans; Todd B. Marder; Marcel A. Duin; Cornelis J. Elsevier; Xavier Baucherel; Arran A. D. Tulloch; Robert P. Tooze

doi:10.1039/B406052K

Platinum catalysed 3,4- and 1,4-diboration of α,β-unsaturated carbonyl compounds using bis-pinacolatodiboron

Nathan J. Bell,^a Andrew J. Cox,^a Neil R. Cameron,^a John S. O. Evans,^a Todd B. Marder,*^a Marcel A. Duin,^b Cornelis J. Elsevier,^b Xavier Baucherel,^c Arran A. D. Tulloch^c and Robert P. Tooze †^c

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* Corresponding authors

^a Department of Chemistry, University Science Laboratories, Durham University, South Road, Durham, UK
E-mail: todd.marder@durham.ac.uk
Fax: +44191 3844737
Tel: +44191 3342037

^b Van't Hoff Institute of Molecular Chemistry, Universiteit van Amsterdam, Nieuwe Achtergracht 166, 1018 Amsterdam, The Netherlands

^c Johnson Matthey Catalysts, PO Box 1, Belasis Avenue, Billingham, Cleveland, UK

Abstract

Bis-pinacolatodiboron reacts with α,β-unsaturated carbonyl compounds to give 1,4- and unprecedented 3,4-additions in the presence of a second generation Pt(0) catalyst at ambient temperature.

Chemical Communications

Platinum catalysed 3,4- and 1,4-diboration of α,β-unsaturated carbonyl compounds using bis-pinacolatodiboron

Abstract

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Platinum catalysed 3,4- and 1,4-diboration of α,β-unsaturated carbonyl compounds using bis-pinacolatodiboron

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