Issue 16, 2004
From the journal:

Chemical Communications

Rigidity extremes in coordination chemistry: a fine energetic balance in the isolation of a trapped ligand inversion intermediate†

Caleb M. May,a   Stephen J. Archibald,b   Adam J. Bridgeman,b   Christopher J. Empsonb  and  Timothy J. Hubin*a  

* Corresponding authors

a Department of Natural Science, McPherson College, McPherson, Kansas, USA 67460
E-mail: hubint@mcpherson.edu
Fax: (+1) 620 241-8443
Tel: (+1) 620 241-3568

b Department of Chemistry, University of Hull, Cottingham Road, Kingston upon Hull, UK

Abstract

An unusual copper(II) complex of a highly rigid and bulky ligand (a macrocycle–glyoxal condensate) has been synthesized and investigated via DFT calculations and structural characterisation.

Graphical abstract: Rigidity extremes in coordination chemistry: a fine energetic balance in the isolation of a trapped ligand inversion intermediate

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Article information

DOI
https://doi.org/10.1039/B405358C
Article type
Communication
Submitted
13 Apr 2004
Accepted
24 May 2004
First published
07 Jul 2004

Chem. Commun., 2004, 1880-1881

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Rigidity extremes in coordination chemistry: a fine energetic balance in the isolation of a trapped ligand inversion intermediate

C. M. May, S. J. Archibald, A. J. Bridgeman, C. J. Empson and T. J. Hubin, Chem. Commun., 2004, 1880 DOI: 10.1039/B405358C

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