Issue 16, 2004

Self-assembly by ligand disassembly?—formation of an unusual dodecanuclear [Co(ii)6Co(iii)6] cluster

Abstract

A sterically encumbered ‘tritopic’ picolinic-dihydrazone ligand reacts with cobalt(II) nitrate in air to give a dodecanuclear [Co(II)6Co(III)6] cluster, in which six ligands are hydrolyzed to mono-carboxylate analogues.

Graphical abstract: Self-assembly by ligand disassembly?—formation of an unusual dodecanuclear [Co(ii)6Co(iii)6] cluster

Article information

Article type
Communication
Submitted
07 Apr 2004
Accepted
25 Jun 2004
First published
20 Jul 2004

Chem. Commun., 2004, 1790-1791

Self-assembly by ligand disassembly?—formation of an unusual dodecanuclear [Co(II)6Co(III)6] cluster

V. A. Milway, L. K. Thompson and D. O. Miller, Chem. Commun., 2004, 1790 DOI: 10.1039/B405131A

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