Issue 13, 2004
From the journal:

Chemical Communications

Low temperature NO disproportionation by Mn porphyrin. Spectroscopic characterization of the unstable nitrosyl nitrito complex MnIII(TPP)(NO)(ONO)

Garik G. Martirosyan,a   Arsen S. Azizyan,a   Tigran S. Kurtikyan*ab  and  Peter C. Ford*c  

* Corresponding authors

a Armenian Research Institute of Applied Chemistry (ARIAC), 375005, Yerevan, Armenia

b Molecular Structure Research Centre NAS, 375014, Yerevan, Armenia
E-mail: tkurt@msrc.am

c Department of Chemistry and Biochemistry, University of California, Santa Barbara, California, 93106
E-mail: ford@chem.ucsb.edu

Abstract

Reaction of NO gas with sublimed layers of the MnIITPP (TPP = meso-tetraphenylporphyrinato2−) at low temperature leads to nitric oxide disproportionation. UV-Vis and FTIR spectroscopy with isotopically substituted nitrogen oxides revealed formation of the unstable species identified as trans-MnIII(TPP)(NO)(ONO).

Graphical abstract: Low temperature NO disproportionation by Mn porphyrin. Spectroscopic characterization of the unstable nitrosyl nitrito complex MnIII(TPP)(NO)(ONO)

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Article information

DOI
https://doi.org/10.1039/B404491F
Article type
Communication
Submitted
05 Mar 2004
Accepted
20 Apr 2004
First published
24 May 2004

Chem. Commun., 2004, 1488-1489

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Low temperature NO disproportionation by Mn porphyrin. Spectroscopic characterization of the unstable nitrosyl nitrito complex MnIII(TPP)(NO)(ONO)

G. G. Martirosyan, A. S. Azizyan, T. S. Kurtikyan and P. C. Ford, Chem. Commun., 2004, 1488 DOI: 10.1039/B404491F

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