Issue 14, 2004
From the journal:

Chemical Communications

Neutral and ionic dissociation patterns in hexacoordinate silicon chelates: a model nucleophilic substitution at pentacoordinate silicon

Boris Gostevskii,ab   Keren Adear,a   Akella Sivaramakrishna,a   Gilad Silbert,a   Dietmar Stalke,c   Nikolaus Kocher,c   Inna Kalikhman*a  and  Daniel Kost*a  

* Corresponding authors

a Department of Chemistry, Ben-Gurion University, Beer-Sheva 84105, Israel

b A. E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch, Russian Academy of Sciences, Irkutsk, Russia

c Institut für Anorganische Chemie der Universität Würzburg, Germany
E-mail: kostd@bgumail.bgu.ac.il, innakal@bgumail.bgu.ac.il

Abstract

A model nucleophilic-displacement reaction coordinate at pentacoordinate silicon is demonstrated by neutral and ionic dissociation equilibria through a stable hexacoordinate complex.

Graphical abstract: Neutral and ionic dissociation patterns in hexacoordinate silicon chelates: a model nucleophilic substitution at pentacoordinate silicon

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Article information

DOI
https://doi.org/10.1039/B404157G
Article type
Communication
Submitted
18 Mar 2004
Accepted
14 May 2004
First published
17 Jun 2004

Chem. Commun., 2004, 1644-1645

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Neutral and ionic dissociation patterns in hexacoordinate silicon chelates: a model nucleophilic substitution at pentacoordinate silicon

B. Gostevskii, K. Adear, A. Sivaramakrishna, G. Silbert, D. Stalke, N. Kocher, I. Kalikhman and D. Kost, Chem. Commun., 2004, 1644 DOI: 10.1039/B404157G

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