Issue 11, 2004
From the journal:

Chemical Communications

Titanocene and zirconocene complexes of a phosphorus analog of an Arduengo's carbene: Application in the synthesis of 1,3-diphosphafulvenes†

Thibault Cantat,a   Nicolas Mézailles,a   Nicole Maigrot,a   Louis Ricarda  and  Pascal Le Floch*a  

* Corresponding authors

a Laboratoire “Hétéroéléments et Coordination”, Departement de Chimie, Ecole Polytechnique, UMR CNRS 7653, 91128 Palaiseau cedex, France
E-mail: lefloch@poly.polytechnique.fr
Fax: (33).01.69.33.39.90
Tel: (33).01.69.33.45.70

Abstract

Titanocene and zirconocene carbene complexes of a phosphorus equivalent of an Arduengo's carbene have been synthesized in the coordination sphere of titanocene and zirconocene and exhibit a nucleophilic character which has been exploited in the synthesis of 1,3-diphosphafulvenes.

Graphical abstract: Titanocene and zirconocene complexes of a phosphorus analog of an Arduengo's carbene: Application in the synthesis of 1,3-diphosphafulvenes

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Article information

DOI
https://doi.org/10.1039/B403436H
Article type
Communication
Submitted
05 Mar 2004
Accepted
07 Apr 2004
First published
04 May 2004

Chem. Commun., 2004, 1274-1275

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Titanocene and zirconocene complexes of a phosphorus analog of an Arduengo's carbene: Application in the synthesis of 1,3-diphosphafulvenes

T. Cantat, N. Mézailles, N. Maigrot, L. Ricard and P. Le Floch, Chem. Commun., 2004, 1274 DOI: 10.1039/B403436H

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