Issue 13, 2004

New synthesis of 1,4-diketones via rhodium-catalysed 1,4 carbonylative addition of arylboronic acids to α,β-unsaturated ketones

Abstract

The reaction of various arylboronic acids with α,β-unsaturated ketones under CO pressure and in the presence of rhodium catalyst yields 1,4-diketones.

Graphical abstract: New synthesis of 1,4-diketones via rhodium-catalysed 1,4 carbonylative addition of arylboronic acids to α,β-unsaturated ketones

Article information

Article type
Communication
Submitted
05 Mar 2004
Accepted
04 May 2004
First published
27 May 2004

Chem. Commun., 2004, 1520-1521

New synthesis of 1,4-diketones via rhodium-catalysed 1,4 carbonylative addition of arylboronic acids to α,β-unsaturated ketones

M. Sauthier, Y. Castanet and A. Mortreux, Chem. Commun., 2004, 1520 DOI: 10.1039/B403415E

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