Issue 11, 2004
From the journal:

Chemical Communications

First cation radical salt of a tetrathiafulvalene–based phosphine metal complex

Narcis Avarvaria  and  Marc Fourmigué*a  

* Corresponding authors

a Laboratoire “Chimie, Ingénierie Moléculaire et Matériaux” (CIMMA), UMR 6200 CNRS-Université d'Angers, UFR Sciences, Bât. K, 2 bd Lavoisier, 49045 Angers, France
E-mail: marc.fourmigue@univ-angers.fr
Fax: (33) 2 41 73 54 05

Abstract

Electrocrystallization of (o-P2)Mo(CO)4, where o-P2 is the tetrathiafulvalene-based chelating diphosphine o-Me2TTF-(PPh2)2, in the presence of the Linquist anion Mo6O192− affords a 2:1 salt, formulated as [(o-P2)Mo(CO)4]2[Mo6O19], with a Heisenberg spin chain magnetic behaviour.

Graphical abstract: First cation radical salt of a tetrathiafulvalene–based phosphine metal complex

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/B403168G
Article type
Communication
Submitted
01 Mar 2004
Accepted
08 Apr 2004
First published
05 May 2004

Chem. Commun., 2004, 1300-1301

Permissions

Request permissions

First cation radical salt of a tetrathiafulvalene–based phosphine metal complex

N. Avarvari and M. Fourmigué, Chem. Commun., 2004, 1300 DOI: 10.1039/B403168G

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements