Abstract
Water adds to the two-electron mixed-valence Ir0,II2 core of Ir2(tfepma)3Cl2 (tfepma = MeN[P(OCH2CF3)2]2) to cleanly generate an IrI,III2 hydride. Dehydrohalogenation across the Ir–Ir bond returns the complex to an Ir0,II2 species.
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Supplementary files
Article information
- Article type
- Communication
- Submitted
- 17 Feb 2004
- Accepted
- 07 Jun 2004
- First published
- 03 Aug 2004
Chem. Commun., 2004, 1958-1959
Permissions
Water addition to a two-electron mixed-valence bimetallic center
A. S. Veige and D. G. Nocera, Chem. Commun., 2004, 1958 DOI: 10.1039/B402426E
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