Issue 7, 2004
From the journal:

Chemical Communications

A mixed-bridging ligand nonanuclear Ru(ii) dendrimer containing a tris- chelating core. Synthesis and redox properties†

Julien Leveque,a   Cécile Moucheron,a   Andrée Kirsch-De Mesmaeker,a   Frédérique Loiseau,b   Scolastica Serroni,b   Fausto Puntoriero,b   Sebastiano Campagna,b   Hélène Nierengartenc  and  Alain Van Dorsselaerc  

a Université Libre de Bruxelles, Laboratory of Organic Chemistry and Photochemistry, CP 160/08, 50 av. F.D. Roosevelt, 1050 Bruxelles, Belgium
E-mail: akirsch@ulb.ac.be
Tel: 32 2 6503017

b Department of Inorganic, Analytical & Physical Chemistry, University of Messina, Via Sperone 31, I-98166 Messina, Italy
E-mail: photochem@chem.unime.it
Tel: 39 090 6765737

c UMR 7509, LSMBO-ECPM, 25 rue Becquerel, 67087 Strasbourg, France
E-mail: vandors@chimie.u-strasbg.fr
Tel: 33 3 88416887

Abstract

The first ligand-cored dendrimer based on branching Ru(II) centers and containing mixed polypyridine bridging ligands has been prepared; redox experiments suggest that the redox-active core is not reduced at the expected potential, probably as a consequence of shielding induced by the rigid dendritic array.

Graphical abstract: A mixed-bridging ligand nonanuclear Ru(ii) dendrimer containing a tris- chelating core. Synthesis and redox properties

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Article information

DOI
https://doi.org/10.1039/B400311J
Article type
Communication
Submitted
09 Jan 2004
Accepted
23 Jan 2004
First published
04 Mar 2004

Chem. Commun., 2004, 878-879

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A mixed-bridging ligand nonanuclear Ru(II) dendrimer containing a tris- chelating core. Synthesis and redox properties

J. Leveque, C. Moucheron, A. Kirsch-De Mesmaeker, F. Loiseau, S. Serroni, F. Puntoriero, S. Campagna, H. Nierengarten and A. Van Dorsselaer, Chem. Commun., 2004, 878 DOI: 10.1039/B400311J

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