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Issue 8, 2004
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The first biosynthetic studies of the azinomycins: acetate incorporation into azinomycin B

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Abstract

13 C-Labelled acetate efficiently labels the antitumour natural product azinomycin B, revealing a polyketide origin for the naphthoate fragment, that threonine is the probable precursor of the enol fragment, and that α-ketoglutarate is a probable precursor of the aziridine fragment.

Graphical abstract: The first biosynthetic studies of the azinomycins: acetate incorporation into azinomycin B

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Supplementary files

Article information


Submitted
07 Jan 2004
Accepted
01 Mar 2004
First published
19 Mar 2004

Chem. Commun., 2004, 990-991
Article type
Communication

The first biosynthetic studies of the azinomycins: acetate incorporation into azinomycin B

C. Corre and P. A. S. Lowden, Chem. Commun., 2004, 990 DOI: 10.1039/B400093E

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