Platinum(ii)-bis(9-methyladenine) complexes; N1→N6 migration of Pt(ii) vsdeamination of coordinated methyladenine†
Abstract
Stepwise migration of coordinated Pt(II) from the endocyclic N1 site to the exocyclic amino group occurs in the bis(9-methyladenine-N1) complex of cis-PtII(NH3)2 in basic solution, whereafter