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Issue 6, 2004
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Diastereospecific synthesis of phosphinidene-capped cyclodextrins leading to “introverted” ligands

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Abstract

α-Cyclodextrins (α-CDs) containing “PPh” units which cap the primary face of the CD were obtained in high yield by reaction of Li2PPh with A,B- or A,C-dimesylated and A,B,D,E-tetramesylated precursors; the resulting phosphines are diastereomerically pure and constitute valuable precursors for the synthesis of metallo-cavitands.

Graphical abstract: Diastereospecific synthesis of phosphinidene-capped cyclodextrins leading to “introverted” ligands

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Publication details

The article was received on 04 Dec 2003, accepted on 30 Jan 2004 and first published on 20 Feb 2004


Article type: Communication
DOI: 10.1039/B315802K
Citation: Chem. Commun., 2004,0, 634-635

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    Diastereospecific synthesis of phosphinidene-capped cyclodextrins leading to “introverted” ligands

    E. Engeldinger, L. Poorters, D. Armspach, D. Matt and L. Toupet, Chem. Commun., 2004, 0, 634
    DOI: 10.1039/B315802K

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