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Issue 5, 2004
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Preparation of chiral triarylphosphines by Pd-catalysed asymmetric P–C cross-coupling

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Abstract

Enantioselective C–P cross-coupling of diarylphosphines and ortho-substituted aryl iodides has been achieved with >90%ee, using an in situ catalyst prepared from Et,Et-FerroTANE, Pd2(dba)3×CHCl3 and LiBr.

Graphical abstract: Preparation of chiral triarylphosphines by Pd-catalysed asymmetric P–C cross-coupling

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Article information


Submitted
20 Nov 2003
Accepted
14 Jan 2004
First published
03 Feb 2004

Chem. Commun., 2004, 530-531
Article type
Communication

Preparation of chiral triarylphosphines by Pd-catalysed asymmetric P–C cross-coupling

C. Korff and G. Helmchen, Chem. Commun., 2004, 530
DOI: 10.1039/B315009G

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