Issue 3, 2004
From the journal:

Chemical Communications

Oxygenation of thiolates to S-bonded sulfinate in an iron(iii) complex related to nitrile hydratase

Erwan Galardon,a   Michel Giorgib  and  Isabelle Artaud*a  

* Corresponding authors

a Laboratoire de Chimie et Biochimie Toxicologiques et Pharmacologiques, UMR8601 CNRS, Université René Descartes, 45 rue des St-Pères, 75270 Paris Cedex 06, France
E-mail: isabelle.artaud@biomedicale.univ-paris5.fr
Fax: 33-1-42868387
Tel: 33-1-42862189

b Laboratoire de Bioinorganique Structurale, UMR6517 CNRS, Faculté des Sciences et Techniques de St Jérôme, case 432, avenue Escadrille Normandie-Niemen 13397 Marseille Cedex 20, France

Abstract

Air oxidation of the iron(III) complex derived from (2-mercaptoisobutyryl)-4,5-dichloro-o-phenylenediamine in the presence of Et4NCN afforded the corresponding disulfinato species. With two carboxamido nitrogens trans to two S-bonded sulfinates, this complex mimics the disulfinate inactive form of Fe-NHase.

Graphical abstract: Oxygenation of thiolates to S-bonded sulfinate in an iron(iii) complex related to nitrile hydratase

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Article information

DOI
https://doi.org/10.1039/B312318A
Article type
Communication
Submitted
08 Oct 2003
Accepted
21 Nov 2003
First published
16 Dec 2003

Chem. Commun., 2004, 286-287

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Oxygenation of thiolates to S-bonded sulfinate in an iron(III) complex related to nitrile hydratase

E. Galardon, M. Giorgi and I. Artaud, Chem. Commun., 2004, 286 DOI: 10.1039/B312318A

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