Issue 5, 2004
From the journal:

Chemical Communications

From metal to ligand electroactivity in nickel(ii) oxamato complexes†

Xavier Ottenwaelder,a   Rafael Ruiz-García,‡a   Geneviève Blondin,a   Rosa Carasco,a   Joan Cano,a   Doris Lexa,b   Yves Journauxa  and  Ally Aukauloo*a  

* Corresponding authors

a Laboratoire de Chimie Inorganique, Bât. 420, Université Paris–Sud, 91405 Orsay, France
E-mail: aukauloo@icmo.u-psud.fr
Fax: +33 169154754
Tel: +33 169154755

b Laboratoire de Bioénergétique et Ingénierie des Protéines, 31 chemin Joseph Aiguier, 13402 Marseille Cedex 20, France

Abstract

The locus of oxidation in square-planar nickel(II) oxamato complexes can be continuously shifted from the metal to the ligand by an appropriate choice of electron-donating substituents on the aromatic moiety of the ligand.

Graphical abstract: From metal to ligand electroactivity in nickel(ii) oxamato complexes

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Article information

DOI
https://doi.org/10.1039/B312295F
Article type
Communication
Submitted
03 Oct 2003
Accepted
30 Oct 2003
First published
11 Dec 2003

Chem. Commun., 2004, 504-505

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From metal to ligand electroactivity in nickel(II) oxamato complexes

X. Ottenwaelder, R. Ruiz-García, G. Blondin, R. Carasco, J. Cano, D. Lexa, Y. Journaux and A. Aukauloo, Chem. Commun., 2004, 504 DOI: 10.1039/B312295F

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