Issue 2, 2004
From the journal:

Chemical Communications

Synthesis and ring opening reactions of a 2-silabicyclo[2.1.0]pentane†

Gerhard Maas,*a   Birgit Daucher,a   Alexandra Maiera  and  Voker Gettwerta  

* Corresponding authors

a Division of Organic Chemistry I, University of Ulm, Albert-Einstein-Allee 11, D-89081 Ulm, Germany
E-mail: gerhard.maas@chemie.uni-ulm.de
Fax: +49 (0)731 50 22803
Tel: +49 (0)731 50 22790

Abstract

Methyl 2-silabicyclo[2.1.0]pentane-1-carboxylate, obtained by a photochemical intramolecular cyclopropanation reaction of an α-allylsilyl-α-diazoacetate, undergoes ring opening reactions under different conditions leading to methyl 2-[diisopropyl(methoxy)silylmethyl]cyclopropane-1-carboxylate, a 1-sila-4-cyclopentene-2-carboxylate or an allyl(methoxysilyl)ketene.

Graphical abstract: Synthesis and ring opening reactions of a 2-silabicyclo[2.1.0]pentane

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Article information

DOI
https://doi.org/10.1039/B312110K
Article type
Communication
Submitted
30 Sep 2003
Accepted
22 Oct 2003
First published
03 Nov 2003

Chem. Commun., 2004, 238-239

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Synthesis and ring opening reactions of a 2-silabicyclo[2.1.0]pentane

G. Maas, B. Daucher, A. Maier and V. Gettwert, Chem. Commun., 2004, 238 DOI: 10.1039/B312110K

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