Issue 1, 2004
From the journal:

Chemical Communications

Regio- and enantioselective iridium-catalysed allylic aminations and alkylations of dienyl esters

Gunter Lipowskya  and  Günter Helmchen*a  

* Corresponding authors

a Organisch-Chemisches Institut der Ruprechts-Karls-Universität Heidelberg, Im Neuenheimer Feld 270, D-69120 Heidelberg, Germany
E-mail: g.helmchen@urz.uni-heidelberg.de
Fax: +49 6221 544205
Tel: +49 6221 548401

Abstract

Regio- and enantioselective iridium-catalysed allylic aminations and alkylations of dienyl substrates are presented; using phosphorus amidite L1 as ligand, aminations provided ee values of up to 97% and alkylations of up to 90%.

Graphical abstract: Regio- and enantioselective iridium-catalysed allylic aminations and alkylations of dienyl esters

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Article information

DOI
https://doi.org/10.1039/B311502J
Article type
Communication
Submitted
18 Sep 2003
Accepted
16 Oct 2003
First published
07 Nov 2003

Chem. Commun., 2004, 116-117

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Regio- and enantioselective iridium-catalysed allylic aminations and alkylations of dienyl esters

G. Lipowsky and G. Helmchen, Chem. Commun., 2004, 116 DOI: 10.1039/B311502J

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