Issue 1, 2004

A new route to furanoeremophilane sesquiterpenoids. Synthesis of (±)-6β-hydroxyeuryopsin

Abstract

The naturally occurring furanoeremophilane 6β-hydroxyeuryopsin was synthesized by a novel route which involved Stille coupling of a 2-furylstannane with a cyclohexylmethyl bromide, followed by intramolecular formylation of the furan to complete the tricyclic nucleus of the sesquiterpenoid.

Graphical abstract: A new route to furanoeremophilane sesquiterpenoids. Synthesis of (±)-6β-hydroxyeuryopsin

Supplementary files

Article information

Article type
Communication
Submitted
17 Sep 2003
Accepted
10 Nov 2003
First published
21 Nov 2003

Chem. Commun., 2004, 44-45

A new route to furanoeremophilane sesquiterpenoids. Synthesis of (±)-6β-hydroxyeuryopsin

M. S. Shanmugham and J. D. White, Chem. Commun., 2004, 44 DOI: 10.1039/B311211J

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