Issue 2, 2004
From the journal:

Chemical Communications

Facile alkane functionalization in copper-[2.1.1]-(2,6)-pyridinophane-PhINTs systems†

Andrei N. Vedernikov*a  and  Kenneth G. Caulton*a  

* Corresponding authors

a Department of Chemistry, Indiana University, Bloomington, Indiana 47405

Abstract

Mild catalytic dehydrogenation of cycloalkanes (cyclo-C5H10, cyclo-C6H12, cyclo-C8H16) and aziridination of resulting olefins is reported with PhINTs and copper-[2.1.1]-(2,6)-pyridinophane (L) complexes LCuXn (n = 1, 2; X = Cl, OTf) “activated” with NaBArF4 in dichloromethane solution.

Graphical abstract: Facile alkane functionalization in copper-[2.1.1]-(2,6)-pyridinophane-PhINTs systems

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Article information

DOI
https://doi.org/10.1039/B309519C
Article type
Communication
Submitted
07 Aug 2003
Accepted
31 Oct 2003
First published
08 Dec 2003

Chem. Commun., 2004, 162-163

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Facile alkane functionalization in copper-[2.1.1]-(2,6)-pyridinophane-PhINTs systems

A. N. Vedernikov and K. G. Caulton, Chem. Commun., 2004, 162 DOI: 10.1039/B309519C

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