Jump to main content
Jump to site search

Issue 4, 2004
Previous Article Next Article

Microwave-assisted synthesis of allylic amines: considerable rate acceleration in the hydrozirconation–transmetalation–aldimine addition sequence

Author affiliations

Abstract

The hydrozirconation of alkynes with zirconocene hydrochloride and the dimethylzinc-mediated addition of alkenylzirconocenes to diphenylphosphinoyl imines can be greatly accelerated with microwave irradiation, resulting in a convenient and rapid one-pot process for the preparation of synthetically useful allylic amines.

Graphical abstract: Microwave-assisted synthesis of allylic amines: considerable rate acceleration in the hydrozirconation–transmetalation–aldimine addition sequence

Back to tab navigation

Supplementary files

Publication details

The article was received on 23 Dec 2003, accepted on 19 Jan 2004 and first published on 28 Jan 2004


Article type: Communication
DOI: 10.1039/B316741K
Org. Biomol. Chem., 2004,2, 443-445

  •   Request permissions

    Microwave-assisted synthesis of allylic amines: considerable rate acceleration in the hydrozirconation–transmetalation–aldimine addition sequence

    P. Wipf, J. Janjic and C. R. J. Stephenson, Org. Biomol. Chem., 2004, 2, 443
    DOI: 10.1039/B316741K

Search articles by author

Spotlight

Advertisements