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Issue 2, 2004
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The kinetics of low-temperature oxygen migration in ZrWMoO8

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Abstract

ZrWMoO8 has been shown to undergo a phase transition at remarkably low temperatures in which oxygen atoms become dynamically disordered. The kinetics of this process have been studied by a variety of laboratory-based time and temperature dependent powder diffraction experiments. Oxygen mobility from temperatures as low as 205 K has been confirmed and an activation energy of 34 kJ mol−1 estimated for the migration process.

Graphical abstract: The kinetics of low-temperature oxygen migration in ZrWMoO8

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Article information


Submitted
22 Aug 2003
Accepted
10 Oct 2003
First published
24 Oct 2003

J. Mater. Chem., 2004,14, 151-156
Article type
Paper

The kinetics of low-temperature oxygen migration in ZrWMoO8

S. Allen and J. S. O. Evans, J. Mater. Chem., 2004, 14, 151
DOI: 10.1039/B310137A

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