Theoretical study on photoexcitation dynamics of the K atom attached to helium clusters and the solvation structures of K*Hen exciplexes
Abstract
The dynamics of the K atom attached to the 300-atom helium cluster upon photoexcitation has been studied theoretically based on the quantum molecular dynamics method. With the use of a hybrid method between time-dependent quantum dynamics and semiclassical path integral centroid molecular dynamics, the calculation includes the electronic state