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Issue 21, 2004
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[PtMe(iPr3P)2]+: a Pt(ii) complex with an agostic interaction that undergoes C–H activation

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Abstract

The T-shaped Pt(II) complex [PtMe(iPr3P)2][1-H-closo-CB11Me11], which is stabilised by an agostic interaction, undergoes acid-catalysed intramolecular C–H activation in the presence of THF to afford cyclometallated [Pt(THF)(iPr3P)(iPr2PCHMeCH2)][1-H-closo-CB11Me11].

Graphical abstract: [PtMe(iPr3P)2]+: a Pt(ii) complex with an agostic interaction that undergoes C–H activation

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Article information


Submitted
16 Jul 2004
Accepted
11 Aug 2004
First published
23 Sep 2004

Chem. Commun., 2004, 2398-2399
Article type
Communication

[PtMe(iPr3P)2]+: a Pt(II) complex with an agostic interaction that undergoes C–H activation

M. J. Ingleson, M. F. Mahon and A. S. Weller, Chem. Commun., 2004, 2398
DOI: 10.1039/B410846A

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