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Issue 21, 2004
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Isolation and characterisation of the mixed-metal alkyl amide [(TMEDA)Na(μ-Bu)(μ-TMP)Mg(TMP)], an unexpected chelate-trapped intermediate in the formation of inverse crowns

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Abstract

Only two-fold amination occurs when 3 molar equivalents of TMPH are offered to a 1 ∶ 1 BuNa–Bu2Mg mixture; adding TMEDA gives the mixed alkyl amide [(TMEDA)Na(μ-Bu)(μ-TMP)Mg(TMP)], which itself affords the phenyl-bridged analogue when reacted with benzene.

Graphical abstract: Isolation and characterisation of the mixed-metal alkyl amide [(TMEDA)Na(μ-Bu)(μ-TMP)Mg(TMP)], an unexpected chelate-trapped intermediate in the formation of inverse crowns

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Article information


Submitted
07 Jul 2004
Accepted
17 Aug 2004
First published
23 Sep 2004

Chem. Commun., 2004, 2422-2423
Article type
Communication

Isolation and characterisation of the mixed-metal alkyl amide [(TMEDA)Na(μ-Bu)(μ-TMP)Mg(TMP)], an unexpected chelate-trapped intermediate in the formation of inverse crowns

E. Hevia, D. J. Gallagher, A. R. Kennedy, R. E. Mulvey, C. T. O'Hara and C. Talmard, Chem. Commun., 2004, 2422
DOI: 10.1039/B410293B

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