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Issue 12, 2004
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Thermal and light induced polymorphism in iron(ii) spin crossover compounds

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Abstract

The spin crossover complexes {Fe[H2B(pz)2]2L} ([H2B(pz)2] = dihydrobis(pyrazolyl)borate, L = 2,2′-bipyridine (1), bipy and 1,10-phenanthroline, phen (2)) undergo both thermal and light induced spin crossover, but the structure of the low spin and light induced high spin states for 2 are different from that of the thermally induced high spin state and from those of 1.

Graphical abstract: Thermal and light induced polymorphism in iron(ii) spin crossover compounds

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Article information


Submitted
03 Mar 2004
Accepted
14 Apr 2004
First published
14 May 2004

Chem. Commun., 2004, 1390-1391
Article type
Communication

Thermal and light induced polymorphism in iron(II) spin crossover compounds

A. L. Thompson, A. E. Goeta, J. A. Real, A. Galet and M. Carmen Muñoz, Chem. Commun., 2004, 1390
DOI: 10.1039/B403179B

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