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Issue 6, 2004
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A novel nonanuclear CuII carboxylate-bridged cluster aggregate with an S = 7/2 ground spin state

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Abstract

The CuII aggregate in [Cu9(cpida)6(MeOH)6]·6(MeOH) {H3cpida = 2-(carboxyphenyl)iminodiacetic acid} is made up of two weakly ferromagnetically coupled carboxylate-bridged Cu4 units that are antiferromagnetically linked through a central CuII to give a Cu9 core with an S = 7/2 spin ground state.

Graphical abstract: A novel nonanuclear CuII carboxylate-bridged cluster aggregate with an S = 7/2 ground spin state

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Article information


Submitted
11 Dec 2003
Accepted
26 Jan 2004
First published
23 Feb 2004

Chem. Commun., 2004, 740-741
Article type
Communication

A novel nonanuclear CuII carboxylate-bridged cluster aggregate with an S = 7/2 ground spin state

M. Murugesu, P. King, R. Clérac, C. E. Anson and A. K. Powell, Chem. Commun., 2004, 740
DOI: 10.1039/B316233H

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