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Issue 6, 2004
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Facile protocol for the highly regioselective and stereodivergent synthesis of substituted bishomoallylic alcohols from esters

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Abstract

Regio- and diastereoselective preparation of bishomoallylic alcohols was realized by a facile four-step protocol including α,α′-selective zinc-mediated bispropargylation of unactivated esters and stereoselective reduction of the resulting bishomopropargylic alcohols.

Graphical abstract: Facile protocol for the highly regioselective and stereodivergent synthesis of substituted bishomoallylic alcohols from esters

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Article information


Submitted
03 Dec 2003
Accepted
26 Jan 2004
First published
17 Feb 2004

Chem. Commun., 2004, 692-693
Article type
Communication

Facile protocol for the highly regioselective and stereodivergent synthesis of substituted bishomoallylic alcohols from esters

M. Oestreich and F. Sempere-Culler, Chem. Commun., 2004, 692
DOI: 10.1039/B315758J

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