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Issue 6, 2004
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Facile protocol for the highly regioselective and stereodivergent synthesis of substituted bishomoallylic alcohols from esters

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Abstract

Regio- and diastereoselective preparation of bishomoallylic alcohols was realized by a facile four-step protocol including α,α′-selective zinc-mediated bispropargylation of unactivated esters and stereoselective reduction of the resulting bishomopropargylic alcohols.

Graphical abstract: Facile protocol for the highly regioselective and stereodivergent synthesis of substituted bishomoallylic alcohols from esters

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Publication details

The article was received on 03 Dec 2003, accepted on 26 Jan 2004 and first published on 17 Feb 2004


Article type: Communication
DOI: 10.1039/B315758J
Chem. Commun., 2004, 692-693

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    Facile protocol for the highly regioselective and stereodivergent synthesis of substituted bishomoallylic alcohols from esters

    M. Oestreich and F. Sempere-Culler, Chem. Commun., 2004, 692
    DOI: 10.1039/B315758J

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