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Issue 1, 2004
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Practical synthesis of new and highly efficient ligands for the Suzuki reaction of aryl chlorides

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Abstract

A practical synthesis of a novel class of phosphine ligands, phosphino substituted N-aryl pyrroles (PAP ligands), has been developed. These ligands are applied in the palladium-catalyzed coupling of a variety of aryl and heteroaryl chlorides with phenylboronic acid showing exceedingly high turnover numbers at mild reaction temperatures and even at room temperature.

Graphical abstract: Practical synthesis of new and highly efficient ligands for the Suzuki reaction of aryl chlorides

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The article was received on 15 Sep 2003, accepted on 28 Oct 2003 and first published on 28 Nov 2003


Article type: Communication
DOI: 10.1039/B311268N
Chem. Commun., 2004, 38-39

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    Practical synthesis of new and highly efficient ligands for the Suzuki reaction of aryl chlorides

    A. Zapf, R. Jackstell, F. Rataboul, T. Riermeier, A. Monsees, C. Fuhrmann, N. Shaikh, U. Dingerdissen and M. Beller, Chem. Commun., 2004, 38
    DOI: 10.1039/B311268N

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