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Issue 1, 2004
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Highly enantioselective spiro cyclization of 1,6-enynes catalyzed by cationic skewphos rhodium(I) complex

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Abstract

A cationic rhodium(I) complex having a skewphos ligand is shown to be a highly enantioselective catalyst for asymmetric carbocyclization of 1,6-enynes with tri-substituted olefins to control quaternary stereogenic centers of spiro-rings.

Graphical abstract: Highly enantioselective spiro cyclization of 1,6-enynes catalyzed by cationic skewphos rhodium(i) complex

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Publication details

The article was received on 05 Sep 2003, accepted on 14 Oct 2003 and first published on 07 Nov 2003


Article type: Communication
DOI: 10.1039/B310789B
Chem. Commun., 2004, 98-99

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    Highly enantioselective spiro cyclization of 1,6-enynes catalyzed by cationic skewphos rhodium(I) complex

    K. Mikami, Y. Yusa, M. Hatano, K. Wakabayashi and K. Aikawa, Chem. Commun., 2004, 98
    DOI: 10.1039/B310789B

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