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Issue 22, 2004
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Unprecedented Barbier-type reactions catalysed by titanocene(iii)

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Abstract

Selective Barbier-type allylations, benzylations and propargylations of aldehydes and ketones can be carried out under extremely mild conditions employing titanocene(III) complexes as catalysts. In this way, chiral titanocene catalysts provided yields ranging from 50–80% of optically active products.

Graphical abstract: Unprecedented Barbier-type reactions catalysed by titanocene(iii)

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Article information


Submitted
22 Jul 2004
Accepted
17 Aug 2004
First published
05 Oct 2004

Chem. Commun., 2004, 2628-2629
Article type
Communication

Unprecedented Barbier-type reactions catalysed by titanocene(III)

A. Rosales, J. L. Oller-López, J. Justicia, A. Gansäuer, J. E. Oltra and J. M. Cuerva, Chem. Commun., 2004, 2628
DOI: 10.1039/B411173G

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