A mild and efficient protocol for the conversion of carboxylic acids to olefins by a catalytic decarbonylative elimination reaction

Abstract

A new method for the conversion of aliphatic carboxylic acids to olefins under unprecedented mild conditions is disclosed, wherein the carboxylic acids are converted in situ with pivalic anhydride to the mixed anhydrides, which regioselectively add to a PdCl₂–DPE-Phos catalyst. At a temperature of only 110 °C, smooth decarbonylation and β-hydride elimination occur, and the corresponding olefins along with CO, CO₂ and pivalic acid are liberated.