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Issue 7, 2004
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On/off regulation of catalysis by allosteric control of metal complex nuclearity

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Abstract

The nature of the allosteric metal ion M (Pd2+ or Pt2+) in complexes ML of a polytopic ligand controls uptake of additional Cu2+ ions; while [Cu2Pd(L-4H)]2+ is a highly active catalyst for phosphodiester cleavage, [CuPt(L-4H)] is inactive.

Graphical abstract: On/off regulation of catalysis by allosteric control of metal complex nuclearity

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Supplementary files

Article information


Submitted
11 Dec 2003
Accepted
30 Jan 2004
First published
04 Mar 2004

Chem. Commun., 2004, 880-881
Article type
Communication

On/off regulation of catalysis by allosteric control of metal complex nuclearity

L. Kovbasyuk, H. Pritzkow, R. Krämer and I. O. Fritsky, Chem. Commun., 2004, 880
DOI: 10.1039/B316225G

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