Thermal reactions of an overcrowded germacyclopropabenzene with group 6 metal hexacarbonyl complexes [M(CO)6]				(M = Cr, Mo, and W): a novel mode of CO insertion leading to the formation of cyclic germoxycarbene metal complexes

Tomoyuki Tajima; Takayo Sasaki; Takahiro Sasamori; Nobuhiro Takeda; Norihiro Tokitoh

doi:10.1039/B314010E

Thermal reactions of an overcrowded germacyclopropabenzene with group 6 metal hexacarbonyl complexes [M(CO)₆] (M = Cr, Mo, and W): a novel mode of CO insertion leading to the formation of cyclic germoxycarbene metal complexes†

Tomoyuki Tajima,^a Takayo Sasaki,^a Takahiro Sasamori,^a Nobuhiro Takeda^a and Norihiro Tokitoh*^a

* Corresponding authors

^a Institute for Chemical Research, Kyoto University, Gokasho, Uji, Kyoto 611-0011, Japan
E-mail: tokitoh@boc.kuicr.kyoto-u.ac.jp
Fax: +81 774 38 3209
Tel: +81 774 38 3200

Abstract

Thermal reactions of an overcrowded germacyclopropabenzene with hexacarbonyl complexes of group 6 metals resulted in the formation of the corresponding cyclic germoxycarbene complexes, i.e., 1,2-oxagermolan-5-ylidene pentacarbonyl metal complexes, via a novel mode of CO insertion reaction toward cyclopropabenzene derivatives.

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https://doi.org/10.1039/B314010E

Submitted

04 Nov 2003

Accepted

03 Dec 2003

First published

20 Jan 2004

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Chem. Commun., 2004, 402-403

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Communication

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Thermal reactions of an overcrowded germacyclopropabenzene with group 6 metal hexacarbonyl complexes [M(CO)₆] (M = Cr, Mo, and W): a novel mode of CO insertion leading to the formation of cyclic germoxycarbene metal complexes

T. Tajima, T. Sasaki, T. Sasamori, N. Takeda and N. Tokitoh, Chem. Commun., 2004, 402

DOI: 10.1039/B314010E

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Thermal reactions of an overcrowded germacyclopropabenzene with group 6 metal hexacarbonyl complexes [M(CO)₆] (M = Cr, Mo, and W): a novel mode of CO insertion leading to the formation of cyclic germoxycarbene metal complexes†

Abstract

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Thermal reactions of an overcrowded germacyclopropabenzene with group 6 metal hexacarbonyl complexes [M(CO)₆] (M = Cr, Mo, and W): a novel mode of CO insertion leading to the formation of cyclic germoxycarbene metal complexes

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