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Smart fabrics that reversibly switch between superhydrophobicity and superhydrophilicity were developed using a combination of hierarchical nanostructured fibrous webs and a pH-responsive polymer that experiences pH-dependent conformational transitions, poly[2-(diisopropylamino)ethylmethacrylate-co-3-(trimethoxysilyl)propylmethacrylate].

Graphical abstract: Electrospun smart fabrics that display pH-responsive tunable wettability

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